Resonant soft x-ray scattering revealed liquid crystal structures that cannot be probed using diffraction, including chiral liquid crystal systems such as the “blue phase” and the twist-bend nematic phase. Information on how individual molecules form functional structures in these systems is key to developing new applications. Read more »
Science Briefs
X-Ray Footprinting Solves Mystery of Metal-Breathing Protein
Scientists have discovered the details of an unconventional coupling between a bacterial protein and a mineral that allows the bacterium to breathe when oxygen is not available. The research could lead to innovations in linking proteins to other materials for bioelectronic devices such as sensors that can diagnose disease or detect contaminants. Read more »
Exploring the Roots of Photosynthesis in a Soil-Dwelling Bacterium
The bacterium, H. modesticaldum, is thought to have a photosynthetic reaction center resembling the earliest common ancestor of all photosynthesis complexes. Its molecular structure has now been solved, providing insight into the evolution of photosynthesis and how nature optimized light-driven energy collection. Read more »
Microbes Linked to Drier Human Skin
Genetic analyses and infrared studies have found that archaea, a type of microbe commonly found in extreme environments, are also found on human skin. The results suggest that an increase in archaea is linked to reduced skin moisture and that they are most abundant in subjects younger than 12 and older than 60. Read more »
The Mystery of the Lightweight Electrons
Copper oxides are important for superconductivity applications but are difficult to understand due to complex charge, spin, and orbital interactions. Now, studies at the ALS have found such a system in which observations of effective electron mass are at odds with state-of-the-art electronic-structure calculations. Read more »
Formation of a Photovoltaic Material from Precursor to Crystal
Lead halide perovskites have emerged as high-performance photovoltaic materials, demonstrating remarkably rapid improvements in efficiency. In situ printing and time-resolved x-ray characterization have provided new insights into the relationship between device efficiency, perovskite crystallinity, and film morphology. Read more »
Hybrid LED Phosphors Combine Performance and Durability
Light-emitting diodes (LEDs) last a long time and are very energy efficient. However, white LEDs currently rely on phosphor materials doped with rare-earth elements (REEs) that are increasingly costly and in short supply. A new class of hybrid phosphor materials shows promise as REE-free alternatives. Read more »
The Ancient Roman Secret to Concrete Resilience in Seawater
Researchers used x-ray microdiffraction to trace the complex sequences of crystal growth in concrete from ancient Roman pier and breakwater sites. The results indicate that minerals continue to form over millennia as seawater percolates through, reinforcing the cementing matrix in a kind of regenerative process. Read more »
Fine-Tuning Oxygen Vacancies with Coherent Strain
Researchers have demonstrated a novel way to systematically strain-engineer oxygen vacancies in complex transition-metal oxide thin films. The work advances our ability to tailor such defects, small changes in which can lead to dramatic changes in material properties such as conductivity and magnetism. Read more »
Protein Complex Shows Promise for Berkelium Separation
Scientists found that the element berkelium breaks form with its heavy-element peers by taking on an extra positive charge when bound to a synthetic organic molecule. This property could help scientists develop better methods for handling and purifying nuclear materials. Read more »
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