A Scalable Platform for Two-Dimensional Metals May 21, 2020 - Using a new method for stabilizing a two-dimensional (2D) metal on a large-area platform, researchers probed the origins of the material’s superconductivity. The work represents a notable milestone in advancing 2D materials toward broad applications in topological computing, advanced optics, and molecular sensing. Read more »
A Forked Path for Superconductivity May 15, 2020 - Uranium ditelluride (UTe2) exhibits a form of superconductivity that could, in theory, enable fault-tolerant quantum computing. Angle-resolved photoemission spectroscopy revealed several aspects of the material’s unusual electronic environment, including one-dimensional conducting channels that are orthogonally oriented. Read more »
Divergent Adsorption-Dependent Luminescence of Amino-Functionalized Lanthanide Metal–Organic Frameworks for Highly Sensitive NO2 Sensors May 7, 2020 - A novel gas-sensing mechanism exploiting lanthanide luminescence modulation upon NO2 adsorption is demonstrated. Two isostructural lanthanide MOFs are used, including an amino group as the recognition center for NO2. Energy transfer from the ligands to Ln is strongly dependent on the presence of NO2, resulting in an unprecedented photoluminescent sensing scheme. Read more »
Porous Electrolyte Frameworks for All-Solid-State Batteries April 27, 2020 - With the help of microtomography at the ALS, researchers developed a method to produce a porous electrolyte framework that they used to construct a working all-solid-state battery. Such batteries potentially offer a higher energy density, longer cycle life, and better inherent safety than state-of-the-art lithium-ion batteries. Read more »
Study Leads to Firmer Grasp of Biochemical “Reactive Handle” April 27, 2020 - Protein crystallography provided new insight into a functional group of molecules that, if added to bacterial enzymes, could enable a variety of alterations to the bacteria’s polymer output. Tweaking enzymes to produce these “reactive handles” is a first step toward biosynthesizing diverse polymers with tailored properties. Read more »
Valence tautomerism in a cobalt-verdazyl coordination compound April 25, 2020 - Valence tautomerization in inorganic chemistry typically involves the distribution of electrons between a metal center and redox active ligand, with potential application as molecular switches or other molecular devices. Here we report an example of valence tautomerization and an unusual electronic structure in a cobalt verdazyl complex. Read more »
Direct Imaging of Fracture Closure in Reservoir Shales April 24, 2020 - Using x-ray microtomography at the ALS, researchers identified and characterized the microscale factors affecting fluid flow through shale fractures propped open with sand or ceramic spheres. A better understanding of propped fractures can lead to safer and more efficient recovery of hard-to-reach oil and gas resources. Read more » 
Assembly Lines for Designer Bioactive Compounds April 22, 2020 - Researchers successfully bioengineered changes to a molecular “assembly line” for bioactive compounds, based in part on insights gained from small-angle x-ray scattering at the ALS. The ability to re-engineer these assembly lines could improve their performance and facilitate the synthesis of new medically useful compounds. Read more » 
Highly Enhanced Curie Temperature in Ga‐Implanted Fe3GeTe2 van der Waals Material April 15, 2020 - Researchers report an effective and reliable method of increasing the Curie temperature of ferromagnetic Fe3GeTe2 (FGT) van der Waals (vdW) material by Ga implantation, opening a new opportunity for tailoring the magnetic properties of vdW materials beyond room temperature for future spintronics applications. Read more »
The Inside‐Outs of Metal Hydride Dehydrogenation: Imaging the Phase Evolution of the Li‐N‐H Hydrogen Storage System April 8, 2020 - Hydrogen absorption and release in lithium amide involves chemical and structural change. Scanning transmission x‐ray microscopy visualizes this phase evolution inside particles, showing a core‐shell architecture, with the more hydrogenated species as the shell for hydrogenation and, more surprisingly, for dehydrogenation as well. Read more »