Researchers studied samples from corals, mollusks, and sea urchins, at edges where mineral precursors start to form the new shell or skeleton. There, they found a surprise: corals and mollusks produced a mineral precursor that had never been observed before in living organisms or rocks, and had only recently been created synthetically. Read more »
Mechanics of a Floating Molecular Layer for CO2 Reduction
Researchers discovered how a layer of organic molecules on a nanoparticle surface detaches to create a highly catalytic pocket for reducing CO2 to CO. The ability to probe molecular-scale events under realistic conditions with nanometer resolution will help guide the design of responsive systems for a wide range of applications, from medicine to optoelectronics. Read more »
Shedding Light on Sea Creatures’ Secrets
Exactly how does coral make its skeleton, a sea urchin grow a spine, or an abalone form the mother-of-pearl in its shell? A new study at the ALS revealed that this process of biomineralization, which sea creatures use to lock carbon away in their bodies, is more complex and diverse than previously thought. Read more »
Raman and Far-Infrared Synchrotron Nanospectroscopy of Layered Crystalline Talc: Vibrational Properties, Interlayer Coupling, and Symmetry Crossover
Talc is an electrical insulator and an excellent target for low-cost, heterostructure-based optoelectronic applications. Here, light-matter interactions and their consequences at the nanoscale-thickness limit are probed using Raman spectroscopy, near-field synchrotron infrared nanospectroscopy, and first-principles calculations. Read more »
A Nano-IR Probe for Proteins in Liquid Environments
A new technique using infrared (IR) light revealed how the self-assembly of proteins is affected by environmental conditions in a surrounding liquid. This nanoscale probe of soft matter in a liquid matrix will facilitate advances in biology, plastics processing, and energy-relevant applications such as electrocatalysts and batteries. Read more »
Infrared Probe of Ultrahigh-Quality Nanoribbon Resonators
Researchers found that ribbon-like thin films, grown through a bottom-up, self-assembly approach, can act as ultrahigh-quality nanoscale resonators of lattice vibrations at infrared frequencies. These ultrathin nanostructures are ideal platforms for applications that harness infrared light, such as thermal emission and molecular sensing. Read more »
Site-dependent selectivity in oxidation reactions on single Pt nanoparticles
Heterogeneous catalysis is a surface-controlled phenomenon in which different surface sites often show variations in reactivity, posing a major complication for the chemical industry. Here, site-dependent selectivity in oxidation reactions on Pt nanoparticles was identified by conducting IR nanospectroscopy measurements while using allyl-functionalized N-heterocyclic carbenes (allyl-NHCs) as probe molecules. Read more »
2020 Shirley Award to Honor Miquel Salmeron
By taking surface studies from ultrahigh vacuum to near-ambient pressure, Miquel Salmeron’s work at the ALS has had deep impact on a broad range of scientific questions, revealing the chemical, electronic, and mechanical properties of surfaces and interfaces on the nanometer (and often atomic) scale. Read more »
Survival of T. rex Microvascular Structures from Deep Time
Researchers used several analytical techniques at the ALS to demonstrate how soft-tissue structures may be preserved in dinosaur bones, countering long-standing scientific dogma that protein-based body parts cannot survive more than one million years. Read more »
Berkeley Lab Helps Reveal How Dinosaur Blood Vessels Can Preserve Through the Ages
A team of scientists used infrared and x-ray imaging performed at the Advanced Light Source to determine the chemical mechanisms that allow soft tissue structures to persist in dinosaur bones—countering the long-standing scientific dogma that protein-based body parts can’t survive more than 1 million years. Read more »