Scientists have developed “multielement ink”—the first “high-entropy” semiconductor that can be processed at low temperature or room temperature. The new semiconducting material could accelerate the sustainable production of next-gen microelectronics, photovoltaics, solid state lighting, and display devices. Read more »
Making Renewable, Infinitely Recyclable Plastics Using Bacteria
Scientists engineered microbes to make the ingredients for recyclable plastics—replacing finite, polluting petrochemicals with sustainable alternatives. The new approach shows that renewable, recyclable plastics are not only possible, but also outperform those from petrochemicals. Read more »
Optical sensing of aqueous nitrate anion by a platinum(II) triimine salt based solid state material
Researchers present a new Pt(II) salt that enables the selective and quantitative measurement of aqueous nitrate anions without the need for pH adjustment. The method relies on the color change of the Pt(II) complex from yellow to red and an intense luminescence response, simplifying the detection process for on-site applications and expanding its applicability to broader matrices. Read more »
Valence tautomerism in a cobalt-verdazyl coordination compound
Valence tautomerization in inorganic chemistry typically involves the distribution of electrons between a metal center and redox active ligand, with potential application as molecular switches or other molecular devices. Here we report an example of valence tautomerization and an unusual electronic structure in a cobalt verdazyl complex. Read more »
A New Material System for Mixed-Plastic Recycling
Scientists have designed a new material system to overcome one of the biggest challenges in recycling consumer products: mixed-plastic recycling. Their achievement will help enable a much broader range of fully recyclable plastic products and brings into reach an efficient circular economy for durable goods like automobiles. Read more »
Ionic Conduction Mechanism and Design of Metal–Organic Framework Based Quasi-Solid-State Electrolytes
This cover image demonstrates the critical role of the solvent in the ion motion of intrinsically anionic metal–organic framework (MOF)–based quasi-solid-state electrolytes (QSSEs). Using hybrid theoretical and experimental approaches, we have identified solvent-assisted hopping as the dominant pathway for Li+ conduction in such materials, exemplified by MOF-688. Read more »
A {Ni12}-Wheel-Based Metal–Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide
SO2 and NO2 are important air pollutants, and understanding the mechanism of capture materials drives the development of new clean-up technologies. In situ synchrotron x-ray crystallographic and spectroscopic experiments were used to establish a detailed molecular mechanism consisting of reversible coordination of SO2 and NO2 at the six open NiII sites on the unprecedented {Ni12}-wheel of a robust metal–organic framework material at crystallographic resolution. Read more »
Designing Selective Membranes for Batteries Using a Drug Discovery Toolbox
Researchers designed a polymer membrane with molecular cages built into its pores that hold positively charged ions from a lithium salt. These “solvation cages” increased lithium-ion flow by an order of magnitude and could allow high-voltage battery cells to operate at higher power and more efficiently, important for both electric vehicles and aircraft. Read more »
Molecular Complex Removes Copper Ions from Water
X-ray analyses provided key insights into the copper uptake mechanisms in a new organic-inorganic hybrid material that quickly and selectively removes copper ions from water. The material provides an efficient tool for copper remediation as well as a blueprint for creating other hybrid materials for removing toxic metals from water. Read more »
Scientists Design New Framework for Clean Water
A promising solution to water pollution from abandoned copper mines relies on materials that adsorb copper ions from wastewater, but commercially available products lack the required chemical specificity and load capacity. A team of scientists has designed a new crystalline material that targets and traps copper ions from wastewater with unprecedented precision and speed. Read more »