Aided by x-ray absorption spectroscopy at the ALS, researchers from Toyota and the University of Akron have uncovered a new catalysis mechanism to improve oxidation-reduction reactions in certain fuel cells by 40%. This enhancement, based on tin oxide, will support efforts to increase fuel efficiency in electric vehicles. Read more »
Study Reveals ‘Radical’ Wrinkle in Forming Complex Carbon Molecules in Space
Scientists have identified several avenues by which ringed molecules known as polycyclic aromatic hydrocarbons can form in space. PAHs—which also occur on Earth in emissions and soot from the combustion of fossil fuels—could provide clues to the formation of life’s chemistry in space as precursors to interstellar nanoparticles. Read more »
The Chemistry of Art
To learn more about the chemical processes involved in aging oil paints in microscopic and nanoscale detail, researchers conducted a range of studies that included 3D x-ray imaging of a paint sample. The study could have broader implications for conservation based on the observed chemistry of oil paints. Read more »
Fundamental Property of Arginine Revealed Through Solvation
Just 20 amino acids act as building blocks for all our proteins, but their chemical properties have been difficult to study at the most fundamental level. Combining experiments and theory at the ALS, researchers have now determined the ionization energy of arginine, an amino acid with over 100 isomers. Read more »
Molecular Framework Imparts Stability to Reactive Catalyst
Researchers have shown that a rigid metal–organic framework (MOF) can be used to stabilize core regions of a reactive catalyst that has potential for use in artificial photosynthesis. The framework immobilizes and preserves key reactive intermediates and affords a clearer view of how the catalyst’s structure correlates with function. Read more »
Catalyst Improves Cycling Life of Magnesium/Sulfur Batteries
Magnesium/sulfur batteries hold promise as a safer, energy-dense advancement, but previous iterations have suffered from extremely limited recharging capabilities. Studies at the ALS provided electrochemical insights into battery polarization and revealed how a titanium catalyst activates magnesium/sulfur compounds to improve battery performance. Read more »
Here Comes the Sun: A New Framework for Artificial Photosynthesis
Scientists have long sought to mimic the process by which plants make their own fuel using sunlight, carbon dioxide, and water through artificial photosynthesis devices, but exactly how catalysts work to generate renewable fuel remains a mystery. Now, a study has uncovered new insight into how to better control cobalt oxide, one of the most promising catalysts for artificial photosynthesis. Read more »
A New Path to Carbon Dioxide Transformation
Combining ALS experiments with quantum-mechanical calculations, scientists found dramatic differences in how carbon dioxide (CO2) reactions begin on silver as opposed to copper. Both metals help transform CO2—a greenhouse gas—into more useful forms, and this new atomic-level data could help make the process more efficient. Read more » 
Gas‐Phase Synthesis of Triphenylene (C18H12)
The cover image shows the triphenylene molecule as a potential precursor to two‐dimensional graphite nanosheets in the interstellar medium. The barrier‐less, exoergic nature of the reaction reveals a versatile reaction mechanism that may drive molecular mass growth processes in cold environments in deep space. Read more »
Plumbing the Depths of Interfaces and Finding Buried Treasure
Understanding the interfaces where solids and liquids meet is key to controlling a wide range of energy-relevant processes, from how batteries store energy to how metals corrode, and more. Now researchers have explored such interfaces and found what they describe as a treasure trove of unexpected results that expands our understanding of working interfaces and how to probe them. Read more »
- 1
- 2
- 3
- …
- 5
- Next Page »
