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ALS Work Using Spectroscopy

These techniques are used to study the energies of particles that are emitted or absorbed by samples that are exposed to the light-source beam and are commonly used to determine the characteristics of chemical bonding and electron motion.

 

Manganese Cathodes Could Boost Lithium-ion Batteries

Rechargeable lithium-ion batteries are used in mobile devices, electric vehicles, and energy storage systems. But supplies of nickel and cobalt, commonly used in the cathodes of these batteries, are limited. New research opens up a potential low-cost, safe alternative in manganese, the fifth most abundant metal in the Earth’s crust. Read more »

A New Way to “Squeeze” Infrared Wavelengths Down to Size

Researchers demonstrated a new way to confine, or “squeeze,” infrared light by coupling photons with phonons (lattice vibrations) within a certain type of thin film. The work heralds a new class of optical materials for controlling infrared light, with potential applications in photonics, sensors, and microelectronic heat management. Read more »PPT-icon-35 PDF-icon-35

4f-Orbital Mixing Increases the Magnetic Susceptibility of Cp’3Eu

The ability to harness the 4f-orbital anisotropies and magnetic susceptibilities of lanthanide elements is key to their application in molecular magnetism, including as molecular qubits and single-molecule magnets. Here, 4f orbital mixing and its impact on the magnetic susceptibility of a trivalent Eu organometallic complex was analyzed experimentally. Read more »

Strategic ALS Projects Reach Key Milestones

Thanks to the hard work and dedication of multidisciplinary teams from groups across the ALS, a spate of important milestones occurred over the past month, for projects involving the new QERLIN beamline, the MERLIN beamline upgrade, and a new chamber for computer-chip metrology in Sector 12. Read more »

Stabilizing Pristine α-Sn Thin Films for Topological Investigation

Researchers developed a recipe for the room-temperature stabilization of thin films of α-Sn, a form of elemental tin that exhibits a variety of topologically nontrivial phases, but only at low temperatures. By dramatically reducing contamination from the film’s substrate, the recipe greatly simplifies electronic structure studies. Read more »PPT-icon-35

Surprise Mineral Precursor Found in Coral Skeletons and Mollusk Shells

Researchers studied samples from corals, mollusks, and sea urchins, at edges where mineral precursors start to form the new shell or skeleton. There, they found a surprise: corals and mollusks produced a mineral precursor that had never been observed before in living organisms or rocks, and had only recently been created synthetically. Read more »

Probing the Liquid/Vapor Interface of a Tunable Solvent

Despite the ready tunability and industrial promise of deep eutectic solvents (DESs), there have been few x-ray spectroscopy studies at their liquid/vapor interfaces—which is relevant for their use in applications such as greenhouse-gas capture. Here, researchers probed the liquid/vapor interface of a benchmark DES using complementary spectroscopies. Read more »

Mechanics of a Floating Molecular Layer for CO2 Reduction

Researchers discovered how a layer of organic molecules on a nanoparticle surface detaches to create a highly catalytic pocket for reducing CO2 to CO. The ability to probe molecular-scale events under realistic conditions with nanometer resolution will help guide the design of responsive systems for a wide range of applications, from medicine to optoelectronics. Read more »PPT-icon-35 PDF-icon-35

Room-Temperature 2D Magnet: Electronic-Structure Insights

Researchers found that small changes in how electron spins interact with each other can make a big difference in the magnetic transition temperatures of 2D magnets. Understanding such factors can help create better magnetic materials for information storage, sensors, medical imaging, and energy-efficient computing. Read more »PPT-icon-35 PDF-icon-35