Fluoride ions show promise as charge carriers in batteries but have limited cyclability. Here we show the reversible and homogeneous topochemical insertion/deinsertion and bulk diffusion of F ions within the one-dimensional tunnels of submicrometer-sized FeSb2O4 particles at room temperature. Read more »
ALS Work Using XAS
In x-ray absorption spectroscopy (XAS), the incident x-ray energy is tuned over a range that will excite core-level electrons. Sharp increases in absorption occur at specific energies, characteristic of the absorbing element. The resulting spectra probe the elemental composition as well as the chemical and electronic structure of the material.
Unexpected Rise in Ferroelectricity as Material Thins
Researchers showed that hafnium oxide surprisingly exhibits enhanced ferroelectricity (reversible electric polarization) as it gets thinner. The work shifts the focus of ferroelectric studies from more complex, problematic compounds to a simpler class of materials and opens the door to novel ultrasmall, energy-efficient electronics. Read more »
The Bottleneck Step of a Complex Catalytic Reaction
The rate-limiting step in catalysis involving oxygen uptake was identified through analysis of the reaction pathways and observations performed under operating conditions. The work lays the foundation for improving the efficiency of energy conversion and storage devices such as fuel cells, catalytic reactors, and batteries. Read more »
How a New Electrocatalyst Enables Ultrafast Reactions
With key data from the ALS, researchers discovered how a new, low-cost electrocatalyst enables an important oxygen reaction to proceed at an ultrafast rate. The work provides rational guidance for the development of better electrocatalysts for applications such as hydrogen-fuel production and long-range batteries for electric vehicles. Read more »
Anomalous Orbital Structure in Two-Dimensional Materials
Researchers explored how structural distortions of the atomic lattice influence exotic electronic states in two-dimensional transition-metal dichalcogenides (TMDs). Polarization-dependent spectroscopy revealed an unexpectedly large crystal-field splitting of the valence electron states, a result of strong hybridization in metal–chalcogen orbitals. Read more »
Multimodal Study of Ion-Conducting Membranes
Using multiple x-ray characterization tools, researchers showed how chemical and structural changes improve the performance of a novel ion-conducting polymer (ionomer) membrane from 3M Company. The work provides insight into factors impacting the proton conductivity of ionomers used for fuel cells and the production of hydrogen fuel. Read more » 
ALS Confirms Mechanism for Improved Fuel Cell Catalysis
Aided by x-ray absorption spectroscopy at the ALS, researchers from Toyota and the University of Akron have uncovered a new catalysis mechanism to improve oxidation-reduction reactions in certain fuel cells by 40%. This enhancement, based on tin oxide, will support efforts to increase fuel efficiency in electric vehicles. Read more »
Controlling Spin in Antiferromagnetic Nanostructures
Researchers discovered that the spin configuration of a nanostructured antiferromagnetic material can be affected by the dimensions of features imprinted onto the material. The results suggest that nanoscale patterning can be a viable tool for engineering spin configurations in future antiferromagnetic spintronic devices. Read more »
Chemical and Morphological Origins of Improved Ion Conductivity in Perfluoro Ionene Chain Extended Ionomers
Resonant x-ray scattering and x-ray absorption spectroscopy with elemental sensitivity unravel structural features tied to water–ion domains and discern sulfur-containing groups in sulfonated ionomers, which help delineate chemical factors controlling their phase-separated morphology and governing ion transport. Read more »
Molecular Framework Imparts Stability to Reactive Catalyst
Researchers have shown that a rigid metal–organic framework (MOF) can be used to stabilize core regions of a reactive catalyst that has potential for use in artificial photosynthesis. The framework immobilizes and preserves key reactive intermediates and affords a clearer view of how the catalyst’s structure correlates with function. Read more »
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