Magnesium/sulfur batteries hold promise as a safer, energy-dense advancement, but previous iterations have suffered from extremely limited recharging capabilities. Studies at the ALS provided electrochemical insights into battery polarization and revealed how a titanium catalyst activates magnesium/sulfur compounds to improve battery performance. Read more »
ALS Work Using XAS
In x-ray absorption spectroscopy (XAS), the incident x-ray energy is tuned over a range that will excite core-level electrons. Sharp increases in absorption occur at specific energies, characteristic of the absorbing element. The resulting spectra probe the elemental composition as well as the chemical and electronic structure of the material.
Here Comes the Sun: A New Framework for Artificial Photosynthesis
Scientists have long sought to mimic the process by which plants make their own fuel using sunlight, carbon dioxide, and water through artificial photosynthesis devices, but exactly how catalysts work to generate renewable fuel remains a mystery. Now, a study has uncovered new insight into how to better control cobalt oxide, one of the most promising catalysts for artificial photosynthesis. Read more »
Evidence of a Long-Predicted Magnet
Half a century ago, theorists proposed a novel way for materials to produce a magnetic field. Now, scientists have discovered a uranium compound that bears out that long-ago theory—a new type of magnet that holds promise for enhancing the performance of data storage technologies. Read more »
Plumbing the Depths of Interfaces and Finding Buried Treasure
Understanding the interfaces where solids and liquids meet is key to controlling a wide range of energy-relevant processes, from how batteries store energy to how metals corrode, and more. Now researchers have explored such interfaces and found what they describe as a treasure trove of unexpected results that expands our understanding of working interfaces and how to probe them. Read more »
Getting to the Bottom of a Metal/Acid Interface
Researchers identified the molecules that collect at the interface between a platinum electrode and an acidic electrolyte under an applied voltage. Knowledge of the structure and composition of such nanometer-thin interface regions is key to understanding topics such as corrosion, geochemistry, electrocatalysis, and energy storage. Read more »
Tunable Ferromagnetism in a 2D Material at Room Temperature
Researchers combined soft x-ray spectroscopy and microscopy to demonstrate the tunable ferromagnetic characteristics of a two-dimensional layered material at room temperature. The results open up exciting opportunities for the use of such materials in low-power spintronics, high-density magnetic storage, and flexible electronics. Read more »
Pupa Gilbert to Receive the 2018 Shirley Award
Pupa Gilbert, professor of physics at the University of Wisconsin at Madison, is the 2018 recipient of the David A. Shirley Award for Outstanding Scientific Achievement at the ALS, “for her development of polarization-dependent imaging contrast mapping to image the orientation of carbonate nanocrystals in marine biominerals.” Read more »
New Manganese Materials Bolster Cathode Capacity
The most expensive component of a battery, the cathode, requires rare transition metals like cobalt. Previous attempts to replace cobalt with inexpensive and non-toxic manganese delivered insufficient performance. Now, researchers have optimized the composition of high-energy-density, high-capacity manganese-based cathodes. Read more »
Oxygen Vacancies Matter in the LaNiO3 Metal–Insulator Transition
Electronic structure measurements using x-ray absorption spectroscopy suggest that oxygen vacancies contribute to the metal–insulator transition in ultrathin films of LaNiO3. The results give scientists another “knob” to turn to tune this important transition, which could be useful for making advanced electronic devices. Read more »
Graphene-Based Catalyst Improves Peroxide Production
Scientists characterized a graphene-based electrocatalyst that potentially makes the production of hydrogen peroxide more selective, efficient, and cost effective. Hydrogen peroxide is an important commodity chemical with growing demand in many areas, including the electronics industry, wastewater treatment, and paper recycling. Read more »
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