Microscopy, spectroscopy, and computational studies of a promising artificial-photosynthesis material led researchers to develop a model photoelectrochemical (PEC) cell with remarkable stability and longevity as it selectively converts sunlight and carbon dioxide into two promising sources of renewable fuels—ethylene and hydrogen. Read more »
New Device Advances Commercial Viability of Solar Fuels
A Berkeley Lab research team developed a new artificial photosynthesis device component that exhibits remarkable stability and longevity as it selectively converts sunlight and carbon dioxide into two promising sources of renewable fuels—ethylene and hydrogen. Read more »
Direct Observation of Surface-Bound Intermediates During Methanol Oxidation on Platinum Under Alkaline Conditions
A comprehensive mechanism for the methanol oxidation reaction (MOR) in alkaline media is presented, and it is shown that the MOR proceeds via two different pathways (via COad or H3C–Oad intermediates). The latter dominates the overall MOR current, suggesting that the H3C–Oad oxidation could be a viable pathway to accelerate the MOR in alkaline systems. Read more »
Scientists Uncover a Different Facet of Fuel-Cell Chemistry
Solid oxide fuel cells are a promising technology for cleanly converting chemical energy to electrical energy. To improve the efficiency of these devices, researchers studied a model electrode material in a new way—by exposing a different facet of its crystal structure to oxygen gas at operating pressures and temperatures. Read more »
Identifying Ionic and Electronic Charge Transfer at Oxide Heterointerfaces
Researchers identified how ion and electron transfer naturally balance at the LaAlO3/SrTiO3 oxide heterointerface, affecting the band alignment and magnetic signature of the interface. The results show that Sr ions are more mobile at the interface than in the bulk, implicating a high importance of ionic charge transfer in oxide heterostructures. Read more »
A 1-Atom-Deep Look at a Water-Splitting Catalyst
X-ray experiments revealed an unexpected transformation in a single atomic layer of a material that contributed to a doubling in the speed of a chemical reaction—the splitting of water into hydrogen and oxygen gases. This process is a first step in producing hydrogen fuel for applications such as electric vehicles powered by hydrogen fuel cells. Read more »
New Insights into Lithium-Metal Surface Reactions for Next-Generation Batteries
In this work, researchers studied how CO2 gas modifies the chemical composition of lithium-metal surfaces. A better understanding of the interactions between lithium and surrounding gases will help design stabilization strategies and move from lithium-ion technology to high-energy-density technologies based on lithium metal. Read more »
Increasing the Efficiency of CO Catalytic Conversion
Using a combination of tools at the ALS and other facilities, researchers probed specific mechanisms affecting the efficiency of catalysts for CO-to-CO2 conversion. The work brings us closer to the rational design of more effective catalysts for cleaning up toxic CO exhaust and advances our understanding of fundamental catalytic reactions. Read more »
How Water Promotes Catalysis of Methane to Methanol
Researchers unraveled how water helps catalyze the conversion of methane, the main component of natural gas, into methanol, a liquid fuel. The work supports the efficient production of methanol and other useful chemicals and could help reduce the amount of greenhouse gases released by the flaring and venting of methane. Read more »
2020 Shirley Award to Honor Miquel Salmeron
By taking surface studies from ultrahigh vacuum to near-ambient pressure, Miquel Salmeron’s work at the ALS has had deep impact on a broad range of scientific questions, revealing the chemical, electronic, and mechanical properties of surfaces and interfaces on the nanometer (and often atomic) scale. Read more »
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