Researchers used infrared light to investigate the properties of the domain walls that separate electrically polarized (ferroelectric) regions in a rare-earth ferrite material. An understanding of domain-wall behavior is relevant to the development of advanced logic and memory applications for ultralow-power digital devices. Read more »
ALS Work Using Spectroscopy
These techniques are used to study the energies of particles that are emitted or absorbed by samples that are exposed to the light-source beam and are commonly used to determine the characteristics of chemical bonding and electron motion.
Nicotine Protonation in Simulated Vaping Aerosols
To better understand how e-cigarette additives alter nicotine chemistry and users’ perceptions of vaping, researchers used x-ray spectroscopy technology at the Advanced Light Source to analyze the acid-base equilibria of additive-enhanced nicotine in simulated vaping aerosols. Read more »
Sub-4 nm mapping of donor–acceptor organic semiconductor nanoparticle composition
We report, for the first time, sub-4 nm mapping of donor : acceptor nanoparticle composition in eco-friendly colloidal dispersions for organic electronics. This technology shows great promise for the optimization of organic semiconductor blends for organic electronics and photocatalysis and has further applications in organic core–shell nanomedicines. Read more »
SO2 Photodissociation at 193 nm Directly Forms S(3P) + O2(3Σg–): Implications for the Archean Atmosphere on Earth
Sulfur isotope patterns in ancient rock layers inform our understanding of Earth’s Archean atmosphere. Before the Great Oxygenation Event (~2.4 billion years ago), hard ultraviolet light penetrated into the Earth’s surface, photodissociating sulfur dioxide directly to S + O2. This new product channel may help resolve discrepancies in the Earth’s evolutionary history. Read more »
Doped Nickelate Enters a New Phase with Spintronics Potential
Rare-earth nickelates are known to undergo a metal-to-insulator phase transition as temperature decreases, the mechanism of which is not well understood. Here, researchers observed a new low-temperature phase that’s both metallic and antiferromagnetic—an unusual combination with potential value in spintronics. Read more »
Electric Vehicle Batteries Could Get Big Boost With New Polymer Coating
Scientists have developed a conductive polymer coating—called HOS-PFM—that conducts both electrons and ions at the same time. This ensures battery stability and high charge/discharge rates while enhancing battery life. The coating also shows promise as a battery adhesive that could extend the lifetime of a lithium-ion battery from an average of 10 years to about 15 years. Read more »
A 2D Electron Liquid Floats on a Crystal Surface
Researchers discovered a liquid-like layer of electrons that floats on the surface of an unusual crystal and appears to undergo a phase transition upon doping. The system is an ideal platform for studying exotic phenomena involving electrons (e.g. superconductivity) without complications arising from other types of interactions. Read more »
Macromolecular organic matter in samples of the asteroid (162173) Ryugu
We investigated the macromolecular organic matter in samples of the asteroid Ryugu—brought to Earth by the Hayabusa2 spacecraft—measuring its elemental, isotopic, and functional group compositions along with its small-scale structures and morphologies. Analytical methods used included spectro-microscopies, electron microscopy, and isotopic microscopy. Read more »
A Study on the Reaction Mechanism of a Model Organic Cathode in Magnesium-Ion Batteries
Battery and analytical studies of a model benzoquinone-type cathode reveal reversible structural transformations driven by a new precedence of a unique dissolution/precipitation mechanism and raise the question regarding its prevalence in other organic cathode batteries. Read more »
Copper Migrates to Surface of Topological Insulator in Air
An ambient-pressure study of a topological insulator doped with copper revealed that the copper atoms, inserted between the material’s layers, migrate to the surface when exposed to air. The work represents a novel way of modifying the material’s surface composition, which can confer it with new properties such as superconductivity. Read more »
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