Metallic nanocrystals are widely used in catalysis, electronics, photonics, and sensing applications, but our understanding of their stability under operational stresses is limited. These studies of gold nanocrystals at high pressures found that large-scale structural transformation is possible and must be considered at the nanoscale. Read more »
Small but Still Mighty: Ultrafine Grains Produce Ultrastrong Metals
Researchers used in situ high-pressure diffraction to resolve a debate about whether a metal’s strength increases or decreases when its grain size decreases below a critical point. The results indicate that ultrastrong metals for future applications can indeed be achieved through grain-size refinement and grain-boundary engineering. Read more »
Time‐Dependent Cytotoxic Properties of Terpyridine‐Based Copper Complexes
The cover feature picture shows the progressive activation of terpyridine‐based copper(II) compounds that are not cytotoxic against various cell lines after 24 h of incubation but become highly efficient after 72 h of incubation, with IC50 values in the low‐micromolar to nanomolar range. Read more »
Survival of T. rex Microvascular Structures from Deep Time
Researchers used several analytical techniques at the ALS to demonstrate how soft-tissue structures may be preserved in dinosaur bones, countering long-standing scientific dogma that protein-based body parts cannot survive more than one million years. Read more »
Can Minerals in the Earth’s Lower Mantle Store Water?
Earth is considered a watery planet, simply by virtue of the fact that 71% of its surface is covered by oceans. But researchers have discovered that, in the massive volume of material in Earth’s interior, minerals can serve as an important water reservoir, providing a new perspective on our planet’s water budget. Read more »
Water Improves Material’s Ability to Capture CO2
With the help of the ALS, researchers from UC Berkeley and ExxonMobil fine-tuned a material to capture CO2 in the presence of water. The parties have applied for a patent on the material, which was developed for use on the relatively humid flue gases emitted by certain natural gas power plants, a cleaner-burning alternative to coal. Read more »
Probing the Evolution of Photovoltaic Films during the Spin-Coating Process
A new, in-beamline spin-coating platform enabled researchers to probe the structure of a promising photovoltaic material in the crucial early stages of processing. The results demonstrate the power of multimodal in situ techniques as promising tools for optimizing synthesis parameters and, thus, device performance. Read more »
Freeze Frame: Scientists Capture Atomic-Scale Snapshots of Artificial Proteins
Protein-like molecules called polypeptoids have great promise as precision building blocks for creating a variety of designer nanomaterials. In this study, rsearchers used cryo-EM, a technique originally designed to image proteins in solution, as well as x-ray scattering techniques, to characterize the structure of polypeptide nanosheets. Read more »
Argon: Not So Noble in Earth’s Core
Researchers demonstrated the synthesis of a thermodynamically stable compound of argon and nickel at temperatures and pressures representative of the Earth’s core. The ability of argon, a noble gas, to react with other elements under these conditions may help solve outstanding geological questions, including the “missing argon paradox.” Read more »
A High-Pressure Compound of Argon and Nickel: Noble Gas in the Earth’s Core?
Researchers demonstrated the synthesis of a thermodynamically stable compound of Ar and Ni at thermodynamic conditions representative of the Earth’s core. The results suggest that the abundance of Ar in the Earth’s core is beyond a simple solubility of Ar in molten Ni–Fe but in chemical reactions in nature. Read more »
