A new ferroelectric material—grown in the lab from cesium germanium tribromide (CGB)—opens the door to an easier approach to making solar cell devices. Unlike conventional solar materials, CGB crystals are inherently polarized, where one side of the crystal builds up positive charges and the other side builds up negative charges, no doping required. Read more »
Ionic Conduction Mechanism and Design of Metal–Organic Framework Based Quasi-Solid-State Electrolytes
This cover image demonstrates the critical role of the solvent in the ion motion of intrinsically anionic metal–organic framework (MOF)–based quasi-solid-state electrolytes (QSSEs). Using hybrid theoretical and experimental approaches, we have identified solvent-assisted hopping as the dominant pathway for Li+ conduction in such materials, exemplified by MOF-688. Read more »
Jinghua Guo to Receive the 2022 Shirley Award
ALS senior scientist Jinghua Guo is the recipient of this year’s Shirley Award for Outstanding Scientific Achievement at the ALS. Guo is being recognized for pioneering the development of operando soft x-ray spectroscopy, work that’s enabled studies under realistic conditions, which is of great importance in environmental and energy research. Read more »
Copper Doping Improves Sodium-Ion Battery Performance
A big plus for batteries based on sodium over lithium is that sodium is more earth-abundant, which lowers costs and eases environmental and supply-chain concerns. Research to improve the performance of sodium-ion batteries includes this effort to use copper doping of the cathode to enhance oxygen redox reversibility. Read more »
A Machine-Learning Approach to Better Batteries
Researchers extracted the relationship between strain and composition in a battery material by applying machine-learning methods to atomic-scale images. The work could lead to more durable batteries and also highlights the potential of integrating microscopy techniques with machine learning to gain insights into complex materials. Read more »
Looking Inside a Battery with Infrared Light
Researchers have developed a new infrared methodology with unparalleled spatial and chemical imaging capabilities that helps to characterize processes at the interfaces between electrodes and electrolytes, with an eye toward bringing increased safety, lifetime, and energy density to the next-generation solid-state battery market. Read more »
How X-Rays Can Make Better Batteries
In order to help our nation meet its goal of net-zero carbon emissions by 2050, scientists like William Chueh and David Shapiro are working together to come up with new strategies to design safer, long-distance batteries made from sustainable, Earth-abundant materials. They discuss their pioneering work in this Q&A. Read more »
A Photoelectrode Protection Scheme for Solar-Fuel Production
Microscopy, spectroscopy, and computational studies of a promising artificial-photosynthesis material led researchers to develop a model photoelectrochemical (PEC) cell with remarkable stability and longevity as it selectively converts sunlight and carbon dioxide into two promising sources of renewable fuels—ethylene and hydrogen. Read more »
Improving the Efficiency of Atmospheric Water Harvesting
Researchers traced the step-by-step path of water-molecule uptake in a porous compound, then made pinpoint modifications to shape the material’s water-sorption behavior. The results led to improvements in the compound’s efficiency at harvesting water from the air, an important step toward alleviating water shortages in the future. Read more »
Revealing Lithium Metal’s Electronic Structure
Spectroscopy at the ALS and theoretical calculations at the Molecular Foundry revealed the intrinsic spectroscopic signature of lithium metal and explained the origin of previous contradictory reports. The findings provide a benchmark for further studies of lithium compounds towards batteries with higher capacity and energy density. Read more »
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