Researchers have shown that a rigid metal–organic framework (MOF) can be used to stabilize core regions of a reactive catalyst that has potential for use in artificial photosynthesis. The framework immobilizes and preserves key reactive intermediates and affords a clearer view of how the catalyst’s structure correlates with function. Read more »
Mineral Discovery Made Easier: X-Ray Technique Shines a New Light on Tiny, Rare Crystals
Like a tiny needle in a sprawling hayfield, a single crystal grain measuring just tens of millionths of a meter— found in a borehole sample drilled in Central Siberia—had an unexpected chemical makeup. And a specialized x-ray technique in use at the ALS confirmed the sample’s uniqueness and paved the way for its formal recognition as a newly discovered mineral: ognitite. Read more »
Plumbing the Depths of Interfaces and Finding Buried Treasure
Understanding the interfaces where solids and liquids meet is key to controlling a wide range of energy-relevant processes, from how batteries store energy to how metals corrode, and more. Now researchers have explored such interfaces and found what they describe as a treasure trove of unexpected results that expands our understanding of working interfaces and how to probe them. Read more »
Getting to the Bottom of a Metal/Acid Interface
Researchers identified the molecules that collect at the interface between a platinum electrode and an acidic electrolyte under an applied voltage. Knowledge of the structure and composition of such nanometer-thin interface regions is key to understanding topics such as corrosion, geochemistry, electrocatalysis, and energy storage. Read more »
Clarifying the Working Principle of a High-Capacity Battery Electrode
Operando x-ray absorption spectroscopy experiments revealed the electrochemical reaction mechanism of molybdenum disulfide (MoS2) electrodes in lithium-ion battery cells. The work unambiguously clarifies that the MoS2 conversion reaction is not reversible and that the Li2S formed is converted to sulfur in the first charge process. Read more »
Researchers Confirm New 2D Topolgical Insulator
Researchers have established that a particularly stable form of WTe2 is a two-dimensional topological insulator, confirming recent predictions. The findings should provide new opportunities for fundamental studies of topological phenomena and for next-generation spintronic applications. Read more »
New Study on Graphene-Wrapped Nanocrystals Makes Inroads Toward Next-Gen Fuel Cells
A powdery mix of metal nanocrystals wrapped in single-layer sheets of carbon atoms shows promise for safely storing hydrogen for use with fuel cells for passenger vehicles and other uses. Now, a new study provides insight into the atomic details of the crystals’ ultrathin coating and how it serves as selective shielding while enhancing their performance in hydrogen storage. Read more »
Toyota Collaborates with the ALS and Molecular Foundry
Toyota has been working at the ALS for a few years now to gain deeper insight into the chemistry of electrolytes for use in magnesium-ion batteries. The hope is that the research eventually leads to a fully developed magnesium-based battery technology that would replace lithium-ion batteries with essentially twice the energy in the same volume. Toyota hopes to move toward this goal more quickly through a new collaborative research project at the ALS and the Molecular Foundry. Read more »
