Researchers simultaneously monitored both the structure and function of a photovoltaic material as it crystallized from solution. The work raises the prospect of rationally tuning materials for optimal performance in photovoltaics and other light-manipulating devices, including light-emitting diodes, detectors, and lasers. Read more »
New Technique Paves the Way for Perfect Perovskites
A new solar material, organic-inorganic halide perovskites, could one day help the U.S. achieve its solar ambitions and decarbonize the power grid. A recent study reports that manufacturing could be aided by a new instrument that uses invisible x-ray light and visible laser light to probe a perovskite material’s crystal structure and optical properties as it is synthesized. Read more »
Exquisitely Selective CO2 Reduction on Silver
Researchers electrochemically reduced CO2 to CO with nearly perfect selectivity over other products by adding an organic compound to the surface of a silver electrode. With theoretical analyses and ALS data, the work revealed the key role of the microenvironment in promoting the conversion of CO2, a greenhouse gas, into useful products. Read more »
A Properly Tailored Tail Boosts Solar-Cell Efficiency
With the help of structural insights from the ALS, researchers optimized the fit between organic and inorganic ions in a perovskite solar-cell material. The work increased the material’s power-conversion efficiency and stability and opens up a new avenue for improving the current-carrier dynamics of a promising class of materials. Read more »
Designing Selective Membranes for Batteries Using a Drug Discovery Toolbox
Researchers designed a polymer membrane with molecular cages built into its pores that hold positively charged ions from a lithium salt. These “solvation cages” increased lithium-ion flow by an order of magnitude and could allow high-voltage battery cells to operate at higher power and more efficiently, important for both electric vehicles and aircraft. Read more »
Stacking the Deck for Custom-Built Hybrid Materials
Researchers fabricated an electronically coupled heterostructure from a novel semiconducting 2D polymer and a 2D transition metal dichalcogenide. Dramatic optical and electronic changes emerged as polymer thickness decreased, underscoring the potential for the discovery of emergent phenomena in studies of hybrid heterostructures. Read more »
Functionalization of Benzotriazole-Based Conjugated Polymers for Solar Cells: Heteroatom vs Substituents
Understanding the structure-property relationship is important when designing new conjugated polymers for high-efficiency polymer solar cells. Rech et al. systematically explore the impact of a variety of functional groups, including nitrogen heteroatoms, fluorine substituents, and cyano groups. Read more »
Balanced Charge Transport Optimizes Industry‐Relevant Ternary Polymer Solar Cells
In this article, Szymanski et al. develop novel, cost‐effective ternary polymer solar cells printed in semi‐industrial conditions from a relatively benign ink, which do not require any further processing. These solar cells show good stability and efficiency due to balanced charge-carrier mobilities achieved by optimizing the composition and morphology. Read more »
Thermoinduced Crystallization-Driven Self-Assembly of Bioinspired Block Copolymers in Aqueous Solution
Thermoinduced crystallization-driven self-assembly of polypeptoid-based block copolymers results in delicate control over the nanostructure in aqueous solution. This provides a convenient platform for comparing cellular uptake efficiency of nanostructured assemblies with various morphologies that are otherwise similar. Read more »
Long Chains Stabilize Higher-Efficiency Solar Cells
Perovskite thin films have many attractive properties for use in photovoltaics, but their assembly into practical devices has led to trade-offs between efficiency and stability. The addition of surfactant-type molecules with hydrophobic chains helped produce perovskite solar cells that are both efficient and stable. Read more »
