Hybrid supercapacitors (HSCs) integrate the merits of batteries with those of supercapacitors. However, the fraction of active material in HSC electrodes has remained too low for commercial requirements. Now, researchers have found a clever way to increase the active-mass ratio to achieve dramatic improvements in key measures. Read more »
Sub-4 nm mapping of donor–acceptor organic semiconductor nanoparticle composition
We report, for the first time, sub-4 nm mapping of donor : acceptor nanoparticle composition in eco-friendly colloidal dispersions for organic electronics. This technology shows great promise for the optimization of organic semiconductor blends for organic electronics and photocatalysis and has further applications in organic core–shell nanomedicines. Read more »
In Situ and Operando Characterizations of Metal Halide Perovskite and Solar Cells: Insights from Lab-Sized Devices to Upscaling Processes
The performance and stability of metal halide perovskite solar cells strongly depend on precursor materials and deposition methods adopted during the perovskite layer preparation. This review presents an update of studies conducted in situ using a wide range of structural, imaging, and spectroscopic techniques, involving the formation/degradation of halide perovskites. Read more »
Electric Vehicle Batteries Could Get Big Boost With New Polymer Coating
Scientists have developed a conductive polymer coating—called HOS-PFM—that conducts both electrons and ions at the same time. This ensures battery stability and high charge/discharge rates while enhancing battery life. The coating also shows promise as a battery adhesive that could extend the lifetime of a lithium-ion battery from an average of 10 years to about 15 years. Read more »
A Study on the Reaction Mechanism of a Model Organic Cathode in Magnesium-Ion Batteries
Battery and analytical studies of a model benzoquinone-type cathode reveal reversible structural transformations driven by a new precedence of a unique dissolution/precipitation mechanism and raise the question regarding its prevalence in other organic cathode batteries. Read more »
Enhanced low-temperature proton conductivity in hydrogen-intercalated brownmillerite oxide
Solid oxide materials typically need high temperatures to allow appreciable ion transport, limiting their flexibility as electrolytes for energy devices. Lu et al. now show unusually high proton conductivity in a hydrogenated oxide between 40 °C and 140 °C, which they attribute to ordered vacancy channels and high proton concentrations. Read more »
Scientists Grow Lead-Free Solar Material With a Built-In Switch
A new ferroelectric material—grown in the lab from cesium germanium tribromide (CGB)—opens the door to an easier approach to making solar cell devices. Unlike conventional solar materials, CGB crystals are inherently polarized, where one side of the crystal builds up positive charges and the other side builds up negative charges, no doping required. Read more »
Versatile Sequential Casting Processing for Highly Efficient and Stable Binary Organic Photovoltaics
Ideal bulk heterojunction morphology is critical in organic solar cells (OSCs). Here, researchers show how sequential casting improves device performance in both fullerene- and nonfullerene-based systems, in which the donor and acceptor are deposited sequentially. The film spin-coating method is analogous to the traditional Chinese pancake-making process. Read more »
Ionic Conduction Mechanism and Design of Metal–Organic Framework Based Quasi-Solid-State Electrolytes
This cover image demonstrates the critical role of the solvent in the ion motion of intrinsically anionic metal–organic framework (MOF)–based quasi-solid-state electrolytes (QSSEs). Using hybrid theoretical and experimental approaches, we have identified solvent-assisted hopping as the dominant pathway for Li+ conduction in such materials, exemplified by MOF-688. Read more »
Jinghua Guo to Receive the 2022 Shirley Award
ALS senior scientist Jinghua Guo is the recipient of this year’s Shirley Award for Outstanding Scientific Achievement at the ALS. Guo is being recognized for pioneering the development of operando soft x-ray spectroscopy, work that’s enabled studies under realistic conditions, which is of great importance in environmental and energy research. Read more »
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